A survey on passive digital video forgery detection techniques

Digital media devices such as smartphones, cameras, and notebooks are becoming increasingly popular. Through digital platforms such as Facebook, WhatsApp, Twitter, and others, people share digital images, videos, and audio in large quantities. Especially in a crime scene investigation, digital evidence plays a crucial role in a courtroom. Manipulating video content with high-quality software tools is easier, which helps fabricate video content more efficiently. It is therefore necessary to develop an authenticating method for detecting and verifying manipulated videos. The objective of this paper is to provide a comprehensive review of the passive methods for detecting video forgeries. This survey has the primary goal of studying and analyzing the existing passive techniques for detecting video forgeries. First, an overview of the basic information needed to understand video forgery detection is presented. Later, it provides an in-depth understanding of the techniques used in the spatial, temporal, and spatio-temporal domain analysis of videos, datasets used, and their limitations are reviewed. In the following sections, standard benchmark video forgery datasets and the generalized architecture for passive video forgery detection techniques are discussed in more depth. Finally, identifying loopholes in existing surveys so detecting forged videos much more effectively in the future are discussed

A novel and disposable amperometric hydrazine sensor based on polydimethyldiallylamine stabilized copper(II)hexacyanoferrate nanocubes modified screen-printed carbon electrode

© 2017 The Authors. A cubic shaped copper(II)hexacyanoferrate was prepared by wet chemical method by mixing an equimolar concentration of CuCl 2 with K 3 [Fe(CN) 6 ] 2 in the presence of poly(diallyldimethylammonium chloride) (PDDA). The X-ray diffraction, field emission scanning electron microscopy, elementa l analysis, Fourier transform infrared spectroscopy and thermal gravimetric analysis were used to confirm the formation of PDDA stabilized copper(II)hexacyanoferrate nanocubes (PDDA@copper(II)hexacyanoferrate nanocubes). The electrocatalytic behavior of the PDDA@copper(II)hexacyanoferrate nanocubes modified screenprinted carbon electrode (SPCE) towards electrochemical oxidation of hydrazine was studied by cyclic voltammetry (CV). The CV results revealed that PDDA@copper(II)hexacyanoferrate nanocubes modified SPCE exhibits an enhanced electrocatalytic activity and lower oxidation potential towards hydrazine than bare SPCE. Under optimized conditions, amperometric i-t method was used for the determination hydrazine, and PDDA@copper(II)hexacyanoferrate nanocubes modified SPCE can able to detect hydrazine in the linear concentration ranges from 0.03 to 533.6 μM with a detection limit of 10 nM. The PDDA@copper(II)hexacyanoferrate nanocubes modified SPCE is highly selective in the presence of potentially active interfering compounds including high concentration of ascorbic acid. In addition, the developed hydrazine sensor shows acceptable practicality with excellent long-term stability towards the detection of hydrazine

A robust nitrobenzene electrochemical sensor based on chitin hydrogel entrapped graphite composite

© 2017 An amperometric nitrobenzene (NB) sensor has been developed based on a glassy carbon electrode (GCE) modified with the composite of chitin hydrogel stabilized graphite (GR-CHI) composite. The physicochemical characterization confirmed the formation of GR-CHI composite and was formed by the strong interaction between GR and CHI. Furthermore, GR-CHI composite modified GCE was used to study the electrochemical reduction behavior of NB by cyclic voltammetry (CV) and compared with GR and CHI modified GCEs. The CV results confirmed that GR-CHI composite modified electrode has high catalytic ability and lower reduction potential toward NB than other modified electrodes due to the combined unique properties of exfoliated GR and CHI. The GR-CHI composite modified electrode can be able to detect the NB in the linear response range from 0.1 to 594.6 µM with the lower detection limit of 37 nM by amperometric i–t method. The selectivity of the sensor is evaluated in the presence of nitroaromatic, biologically active and dihydroxybenzene compounds. The sensor shows appropriate practicality and good repeatability toward detection of NB in lab water samples

Effect of ammonium based ionic liquids on the rheological behavior of the heavy crude oil for high pressure and high temperature conditions

Heavy crude oil (HCO) production, processing, and transportation forms several practical challenges to the oil and gas industry, due to its higher viscosity. Understanding the shear rheology of this HCO is highly important to tackle production and flow assurance. The environmental and economic viability of the conventional methods (thermal or dilution with organic solvents), force the industry to find an alternative. The present study was constructed to investigate the effect of eco-friendly ionic liquids (ILs) on the HCO's rheology, at high temperature and high pressure. Eight different alkyl ammonium ILs were screened for HCO's shear rheology at the temperatures of 25–100 °C and for pressures 0.1–10 MPa. The addition of ILs reduced the HCO's viscosity substantially from 25 to 33% from their original HCO viscosity. Also, it aids to reduce the yield stress to about 15–20% at all the studied experimental conditions. Furthermore, the viscoelastic property of the HCO was studied for both strain-sweep and frequency-sweep and noticed the ILs helps to increase HCO's loss modulus (G″) by reducing storage modulus (G′), it leads to the reduction of the crossover point around 25–32% than the standard HCO. Mean the ILs addition with HCO converts its solid-like nature into liquid-like material. Besides, the effect ILs chain length was also studied and found the ILs which has lengthier chain length shows better efficiency on the flow-ability. Finally, the microscopic investigation of the HCO sample was analyzed with and without ILs and witnessed that these ILs help to fragment the flocculated HCO into smaller fractions. These findings indicate that the ILs could be considered as the better alternative for efficient oil production, processing, and transportation

Effects of Imidazolium-Based Ionic Liquids on the Rheological Behavior of Heavy Crude Oil under High-Pressure and High-Temperature Conditions

The production, processing, and transportation of heavy crude oil (HCO) is difficult because of its high viscosity. For practical applications, information on the rheological behavior of HCO plays an important role, especially in flow assurance investigations. In this work, six different imidazolium ionic liquids (ILs) were tested for their effects on the rheological behavior of HCO under high-pressure and high-temperature conditions. The rheological studies were carried out at three different pressures (0.1, 5, and 10 MPa) and four experimental temperatures (298.15, 323.15, 348.15, and 373.15 K). The HCO + IL systems showed favorable viscosity reductions of 26.5% and 31.5% for the systems of HCO + 1-butyl-3-methylimidazolium chloride ([BMIM]⁺[Cl]⁻) and HCO + 1-octyl-3-methylimidazolium chloride ([OMIM]⁺[Cl]⁻), respectively, at 298.15 K and 0.1 MPa as compared to the pure HCO system. At 298.15 K and 0.1 MPa, the yield stress of the HCO + IL systems was reduced by about 15–20%, whereas when the temperature was increased to 373.15 K, the yield stress decreased in the range of 25–30% as compared to that of neat HCO. The viscoelastic moduli of the HCO sample at 0.1 MPa, 298.15 K, and about 1.5% strain were found to be <i>G</i>′ (storage modulus) ≈ 11 Pa and <i>G</i>″ (loss modulus) ≈ 7 Pa, indicating that the HCO sample was solidlike, whereas for the HCO + IL systems, the <i>G</i>′ and <i>G</i>″ values were reduced to ∼7 and 3 Pa, respectively. The crossover frequency of the HCO + IL systems was reduced to the range of 25–30% as compared to that of pure HCO. From the various measurements, it was observed that the addition of the ILs to the HCO resulted in improved rheological properties compared to those of the pure HCO system. Further, the results of the microscopic investigation also supported the rheological studies, indicating that the addition of the ILs helped to break the large flocculated structures of HCO into smaller spheres. It was also observed that the IL with the longer alkyl chain length provided greater efficiency in the viscosity reduction with favorable viscoelastic behavior

Use of Aromatic Ionic Liquids in the Reduction of Surface Phenomena of Crude Oil–Water System and their Synergism with Brine

Enhanced oil recovery is governed primarily by the role of interfacial tension between crude oil and water. Interfacial tension (IFT) of the crude oil–water system is one of the vital factors in the analysis of the capillary forces affecting trapped oil within the reservoir rocks. High salinity and temperature of the reservoirs tend to make researchers search for new surfactants to lower the interfacial tension in crude oil–water systems. The current study hopes to create a move toward solving the above problem through the use of aromatic ionic liquids (ILs) based on imidazolium as the cation and various anions such as [Cl]⁻, [Br]⁻, [BF₄]⁻, [H₂PO₄]⁻, [HSO₄]⁻, and [PF₆]⁻ in different concentrations. This work involves the study of the effect of concentration, temperature, time, and brine on the fate of surface tension (SFT) of water and interfacial tension of crude oil–water systems. The present study also addresses the trend in the electrical conductivity of ILs in water along with the effect of temperature and concentration of ILs. The study reveals that these ILs are effective in reducing the SFT and IFT of water and crude oil–water systems at high salinity and temperature conditions. In the IFT measurements, a linear decrement with increase in temperature is observed for crude oil–water in the presence of ILs. The interfacial tension of the various imidazolium-based ionic liquids with the crude oil–water system has been measured as a function of temperature by means of the Wilhelmy plate method. The influence of the nature of cation and anion of ionic liquids and of the chain length on the cationic head of the ILs on interfacial tension is also discussed in detail. At increased salinity conditions, unlike classical surfactants, these ILs are found to be more successful. Enhanced efficiency of the drop in IFT using NaCl and IL mixture has been confirmed by measuring the IFT between crude oil and the aqueous solution of IL. The synergism of salt and IL mixture on the reduction of IFT has been observed

Experimental Investigation on the Effect of Aliphatic Ionic Liquids on the Solubility of Heavy Crude Oil Using UV–Visible, Fourier Transform-Infrared, and ¹³C NMR Spectroscopy

Chemical treatment of aromatic heavier hydrocarbons are traditionally done by using cyclic aromatic nonpolar solvents, such as benzene, xylene, and toluene, which have the capability to dissolve asphaltenes. However, these aromatic solvents are volatile and hazardous and hence not advisable to use. Alternatively, lighter hydrocarbons, such as heptane, hexane, etc., show lesser solubility. It is, therefore, crucial that these problems require intelligent, cost-effective, and innovative solutions. The present work investigates the possible solution for the dissolution of heavy crude oil using the application of eight aliphatic ionic liquids (ILs) along with five solvents, namely, toluene, heptane, decane, ethyl acetate, and hexane. Ionic liquids (ILs) based on [CH₃COO]⁻, [BF₄]⁻, [H₂PO₄]⁻, and [HSO₄]⁻ as anions and with various cations, such as di- and tri-alkyl ammonium, are considered. The enhancement in the solubility of heavy crude oil in solvent + ILs mixture is investigated using Ultraviolet–visible (UV–vis) spectrophotometry, Fourier transform-infrared spectroscopy (FT-IR), and ¹³C-nuclear magnetic resonance (NMR) spectroscopic techniques. The absorbance of the sample solution (heavy crude oil + solvent + IL) is compared with the standard solution (heavy crude oil in neat solvent alone). It is observed that the dissolution of heavy crude oil is more in the solution with IL than with the solvent alone. Solubility of heavy crude oil in solvents increases to about 70% in the presence of ILs. Hold-time study is also performed to understand the maximum time required for efficient dissolution of heavy crude oil. The hold-time study reveals that solubility of heavy crude oil in heptane increased to about 61–222% in the presence of ILs, as compared to 11–16% in the case of standard solution for a prolonged period of 30 days